Batman: Arkham City – Extended Villain Details

This chart lists every villain encountered in Batman: Arkham City, including their encounter type, mission name, location, how they were defeated, and fate.

Enter the Shadows
Main Story Side Mission Optional DLC

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VillainEncounter TypeMission NameLocationHow DefeatedFate
Two-Face (Intro)Main StoryPrologue (Catwoman)CourthouseBeaten by CatwomanCaptured
Joker (Steel Mill)Main StoryAccess Joker's CureSteel MillFought at Steel MillSurvives
PenguinMain StoryRescue Mr. FreezeMuseum (Iceberg Lounge)Defeated at Iceberg LoungeCaptured
Solomon GrundyMain StoryDefeat GrundyMuseum (Boss Arena)Boss fight (electric panels)Destroyed
Mr. FreezeMain StoryRetrieve CureGCPD BuildingBoss fight (strategic)Knocked out
Ra’s al GhulMain StoryDemon TrialsWonder CitySword duel in Wonder CitySurvives
ClayfaceMain StoryFinal ConfrontationMonarch TheatreFinal boss (sword & Lazarus Pit)Destroyed
Joker (Final)Main StoryFinal ConfrontationMonarch TheatreDies from Titan PoisoningDead
DeadshotSide MissionShot in the DarkAmusement MileCaptured during assassination missionCaptured
Mad HatterSide MissionThe Hat TrickMad Hatter's HideoutDefeated after hypnosisCaptured
Victor ZsaszSide MissionCold Call KillerCity-wide (Phone Calls)Tracked via phones & capturedCaptured
Calendar ManSide MissionStory CollectorCourthouse BasementAlready imprisonedImprisoned
HushSide MissionIdentity TheftIdentity Theft ScenesIdentified only (escapes)Escapes
Killer CrocSide MissionKiller Croc EncounterSewersEncounter only (no fight)Survives
BaneSide MissionFragile AllianceSubway StationBetrayed after team-upTrapped
Black MaskSide MissionBlack Mask SecretIndustrial DistrictFound in secret room (no fight)Survives
Poison IvyOptionalOptional SceneBotanical GardensCutscene onlySurvives
Harley QuinnOptionalHarley Quinn's RevengeSteel MillDLC fight with thugsSurvives
Two-Face (Catwoman DLC)DLCCatwoman HeistLoot Vault (Two-Face Hideout)Defeated during heistSurvives